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Strontium oxide[1]
__ Sr2+     __ O2-
Archivo:NaCl polyhedra.png
IUPAC name Strontium oxide
Other names Strontia
Identifiers
CAS number 1314-11-0
Properties
Molecular formula SrO
Molar mass 103.62 g/mol
Appearance colorless cubic crystals
Density 4.70 g/cm3
Melting point

2531°C

Boiling point

> 3000 °C (decomp)

Solubility in water reacts, forms Sr(OH)2
Solubility miscible with caustic potash
slightly soluble in alcohol
insoluble in acetone and ether
Refractive index (nD) 1.810 [2]
Structure
Crystal structure Halite (cubic), cF8
Space group Fm3m, No. 225
Coordination
geometry
Octahedral (Sr2+); octahedral (O2–)
Thermochemistry
Std enthalpy of
formation
ΔfHo298
-592.0 kJ·mol−1
Standard molar
entropy
So298
57.2 J·mol−1·K−1
Specific heat capacity, C 44.3 J·mol−1·K−1
Hazards
EU Index Not listed
Flash point Non-flammable
Related compounds
Other anions Strontium sulfide
Other cations Beryllium oxide
Magnesium oxide
Calcium oxide
Barium oxide
Related compounds Strontium hydroxide
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a strongly basic oxide.

Uses[]

About 8% by weight of television picture tube glass is strontium oxide, which has been the major use of strontium since 1970.[3] Color televisions and other devices containing color cathode ray tubes sold in the United States are required by law to use strontium in the faceplate to block X-ray emission (these X-ray emitting TV's are no longer in production). Lead oxide can be used in the neck and funnel, but causes discoloration when used in the faceplate.[4]

Reactions[]

Elemental strontium is formed when strontium oxide is heated with aluminium in a vacuum.[1]

References[]

  1. 1,0 1,1 Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, FL: CRC Press. pp. 4–87. ISBN 0849305942. 
  2. Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0070494398
  3. Mineral Yearbook 2007:Strontium. United States Geological Survey. Retrieved on 2009-09-14.
  4. (2006). "The characterization of waste cathode-ray tube glass.". Waste management 26 (12): 1468–76. DOI:10.1016/j.wasman.2005.11.017. PMID 16427267. ISSN 0956-053X.

External links[]

Plantilla:Strontium compounds


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